Morphology control in metallosupramolecular assemblies through solvent-induced steric demand
نویسندگان
چکیده
منابع مشابه
1,2-Diazoles: Versatile Tectons for Metallosupramolecular Assemblies
......................................................................................................................................... ii Abbreviations and Atom Colour Scheme .................................................................................... iii Chapter 1: Introduction .............................................................................................................
متن کاملControlling the formation of metallosupramolecular assemblies by metal ionic radii.
The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the size of the metal ion.
متن کاملControlling the formation of metallosupramolecular assemblies by metal ionic radiiw
Controlling the structure of multi-component assemblies is one of the leading challenges for the supramolecular chemist. One of the simplest assemblies is the dinuclear doublestranded helicate, and the rules that govern the formation of this species are largely established. The formation of the helicates’ higher nuclearity cousin, the cyclic helicate, is conversely less well understood. One of ...
متن کاملSteric control of the formation of dinuclear double helicate and dinuclear meso-helicate assemblies.
We describe a ligand system that forms either a dinuclear double helicate or a dinuclear double mesocate dependent upon the size of the metal ion or the steric bulk of the ligand strand.
متن کاملSOP‐GPU: influence of solvent‐induced hydrodynamic interactions on dynamic structural transitions in protein assemblies
Hydrodynamic interactions (HI) are incorporated into Langevin dynamics of the Cα -based protein model using the Truncated Expansion approximation (TEA) to the Rotne-Prager-Yamakawa diffusion tensor. Computational performance of the obtained GPU realization demonstrates the model's capability for describing protein systems of varying complexity (10(2) -10(5) residues), including biological parti...
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ژورنال
عنوان ژورنال: Soft Matter
سال: 2020
ISSN: 1744-683X,1744-6848
DOI: 10.1039/d0sm00537a